Guanidinium 2-(myristoylsulfanyl)ethanesulfonate
نویسندگان
چکیده
In the title compound, CH(6)N(3) (+)·C(16)H(31)O(4)S(2) (-) [systematic name: guanidinium 2-(tetra-deca-noylsulfan-yl)ethane-sulfon-ate], each 2-(myristoyl-thio)-ethane-sulfonate ion displays hydrogen bonding to three guanidinium counter-ions, which themselves display hydrogen bonding to two symmetry-related 2-(myristoylthio)ethanesulfonate ions. Thus each cation forms six N-H⋯O bonds to neighboring anions, thereby self-assembling an extended ladder-type network. The average hydrogen-bond donor-acceptor distance is 2.931 (5) Å. The alkyl chains form the rungs of a ladder with hydrogen-bonding inter-actions forming the side rails.
منابع مشابه
An efficient green synthesis of some new 4H-pyrimido[2,1,b]benzimiazoles and 4H-pyrimido[2,1,b]benzothiazoles promoted by guanidinium chloride
A facile and highly efficient protocol was applied successfully to synthesize 4H-pyrimido[2,1,b]benzimiazoles and 4H-pyrimido[2,1,b]benzothiazoles through one-pot three-component cyclocondensation reactions of 2-aminobenzimidazole or 2-aminobenzothiazole with dimedone and aromatic aldehydes in the presence of guanidinium chloride under solvent-free conditions. The reactions us...
متن کامل2-(2-Furylmethylammonio)ethanesulfonate methanol solvate
The organic mol-ecule of the title compound, C(7)H(11)NO(4)S·CH(3)OH, is a zwitterion and its furan ring displays positional disorder [occupancy 0.563 (5):0.437 (5)]. The crystal structure is extended into a three-dimensional supra-molecular architecture through inter-molecular O-H⋯O and N-H⋯O hydrogen bonds with participation of the methanol solvent mol-ecules.
متن کاملAn efficient green synthesis of some new 4H-pyrimido[2,1,b]benzimiazoles and 4H-pyrimido[2,1,b]benzothiazoles promoted by guanidinium chloride
A facile and highly efficient protocol was applied successfully to synthesize 4H-pyrimido[2,1,b]benzimiazoles and 4H-pyrimido[2,1,b]benzothiazoles through one-pot three-component cyclocondensation reactions of 2-aminobenzimidazole or 2-aminobenzothiazole with dimedone and aromatic aldehydes in the presence of guanidinium chloride under solvent-free conditions. The reactions us...
متن کاملMolecular dynamics studies on the denaturation of polyalanine in the presence of guanidinium chloride at low concentration
Molecular dynamic simulation is a powerful method that monitors all variations in the atomic level in explicit solvent. By this method we can calculate many chemical and biochemical properties of large scale biological systems. In this work all-atom molecular dynamics simulation of polyalanine (PA) was investigated in the presence of 0.224, 0.448, 0.673, 0.897 and 1.122 M of guanidinium chlorid...
متن کاملBis(guanidinium) 4,5-dichlorophthalate monohydrate
In the structure of the title hydrated salt, 2CH(6)N(3) (+)·C(8)H(2)Cl(2)O(4) (2-)·H(2)O, the planes of the carboxyl-ate groups of the dianion are rotated out of the plane of the benzene ring [dihedral angles = 48.42 (10) and 55.64 (9)°]. A duplex-sheet structure is formed through guanidinium-carboxyl-ate N-H⋯O, guanidinium-water N-H⋯O and water-carboxyl-ate O-H⋯O hydrogen-bonding associations.
متن کامل